Instituto Pedro Nunes
IPN     IPN Incubadora

Nanosensing
Semiconductor nanocomposite thin films composed of noble metal nanoparticles dispersed in reactive metal-oxide matrixes for LSPR gas sensing applications

Challenge

The main challenge is the development of alternative concepts for gas sensors, with near-single molecule sensitivity, especially tailored for environmental protection purposes in the automotive sector. The project aims to develop low-cost gas sensors, based on metal-oxide semiconductor (MOS) structures, containing several types of noble metal (NM) nanoparticles (NPs), with near-single molecule sensitivity with large relevance for several industrial sectors.

Solution

MAIN OBJECTIVE: To strengthen research, technological development and innovation.

The research will be focused on noble metal (NM) nanoparticles (NPs) such as Au and Ag, which are oxidation resistant and exhibit uniquely intense LSPR absorption peaks in the visible spectrum. The MOS structures will include oxides such as WO3 Ta2O5, ZnO or SnO2, that show high sensitivity to the upper mentioned gases, which are central concerns not only in automotive industry, but also in several areas of industry and consumer products and health care.
Two complementary methods will be tested to produce the nanostructured films: i) the Co-deposition using a cluster source, for Au or Ag, and reactive sputtering of metal targets in O2 atmosphere, for the matrix and; ii) Co-sputtering using a high-power impulse magnetron sputtering (HIPIMS) source, for the noble metal target, and a conventional/HIPIMS source, for the dielectric matrix (in O2 atmosphere). Fundamental understanding of the LSPR effect and systematization of the consequent sensing ability will be carried out through atomistic calculations, while advanced spectroscopy and microscopy will be used to characterize and materials and their performance so that optimized systems/configurations can be designed and subsequently tested. A proof-of-concept will be implemented and the potential for practical application will be assessed through LSPR sensor prototypes, in particular, for
automotive related ones.

Objectives, Activities and Results expected / achieved

 In update

Project Reference

POCI-01-0145-FEDER-016902

Funding

FEDER
FEDER

Intervention Region

NORTE (49,13%), CENTRO (34,53%), LISBOA (16,34%)

Total Investment

186.408,00

IPN Investment

64.368,00

Total Eligible

180.408,00

IPN Eligible

64.368,00

EC Funding – Total

FEDER - 139.641,60

EC Funding – IPN

FEDER - 54712,80

National public financial support – Total

OE - 40.766,40

National public financial support – IPN

OE - 9.655,20

Duration

42 Meses

Start Date

2016-07-01

End Date

2019-12-31

Approval Date

2016-04-08

Consortium

Universidade do Minho;
IPN;
NOVA.ID.FCT - Associação para a Inovação e Desenvolvimento da FCT;
Centro de Física e Investigação Tecnológica (CEFITEC/FCT/UNL);

Partners

 

Keywords

Surface Plasmon Resonance, Gas sensor, Change of optical characteristics, Cluster gun.